Link: https://superuser.com/questions/849265/is-there-a-difference-between-8-pin-eps12v-and-pci-e-connectors
They may look kinda the same but they are completely different.
Top left connector on the EPS 12V is squared off
PCIe is rounded off in the image
More Info: https://electronics.stackexchange.com/questions/465726/what-are-sense-pins-in-8-pin-pci-express-power-plug
https://www.overclock.net/threads/gpu-and-cpu-power-connections.1773088/